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Plus, a famous movie actress, Olivia Burke, enrolls at NYU in hopes of having a somewhat normal college experience, and is assigned to be Vanessa's roommate.
Ursula, an actress co-starring in Olivia's movie befriends Serena when she is hired as her publicist for an upcoming movie premiere. Lily and Rufus decide to move up their wedding day and Chuck discovers a secret that Carter has been keeping from Serena.
Meanwhile, Dan invites Olivia to meet Rufus and Lily, which leads to all sorts of problems for the new couple.
Elsewhere, Serena and Nate team up to help Carter and free him from his arrangement with the Buckleys: but Nate has a different plan in mind Title comes from the 1950 film All About Eve.
Elsewhere, Rufus tries to gets Lily into the Halloween spirit.
Although this is the least watched season to date, with an average of 2.02 million of viewers tuning in each week, it is the highest rated with a 1.1 rating in Adult 18-49.Olivia says something she regrets during an appearance on Jimmy Fallon's talk show and tries to keep Dan from finding out.With election day around the corner, Nate suspects his grandfather will stop at nothing to get his cousin Tripp elected to Congress.Georgina takes an interest in Dan, and Vanessa begins to suspect that something isn't quite right with Scott.
Finally, Bree's true intentions with Nate are revealed. It's the first day of school at Constance Billard which means it's also time for Jenny to take her place as the new Queen Bee.
In the midst of another feud with Serena, Blair befriends a new girl and takes her to an election night party at Chuck's hotel, hoping to make Serena jealous.